Nanoscale Iron for In Situ Environmental Remediation Projects
Manufactured by
Polyflon Company
A Crane Co. company
One Willard Road
Norwalk, CT 06851 USA



Polyflon PolyMetallix Particles
Activated Metal Oxide #0001

Original Date:  8/01/2003
Revision Date: 
2/25/2004

EMERGENCY TELEPHONE:  8:00 AM – 5:00 PM (M-F): (203) 840-7555 
24 HOUR CHEMTREC:  (800) 242-9300 

SECTION 1 - PRODUCT INFORMATION
_____________________________________________________________ Metalized Oxide

Product ID: 0001
Common Chemical Name: None
Molecular Formula: FeO.Fe(2)O(3).Fe(3)O(4).Fe
Chemical Family: Iron oxide and Iron
Molecular Wt.: 232.0 and 58.69

SECTION 2 - INGREDIENTS
______________________________________________________________________
Chemical Name:                                CAS                          Amount
FeO.Fe(2)O(3).Fe(3)O(4)          12227-89-3, 1317-61-9      40.0% to 90.0%

Fe                                                7439-89-6                  10.0% to 60.0%
PEL/TLV NOT ESTABLISHED

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SECTION 3 - HAZARDS IDENTIFICATION
______________________________________________________________________
Emergency Overview
Color:  Black
Form/Appearance:  Paste or Suspension in Water
Odor:  Odorless
WARNING STATEMENT:

CAUTION:
CONTACT WITH THE EYES AND SKIN MAY RESULT IN MECHANICAL IRRITATION.    INHALATION OF THE MIST MAY RESULT IN RESPIRATORY IRRITATION.  INGESTION MAY RESULT IN GASTRIC DISTURBANCES.  CHRONIC OVEREXPOSURE TO IRON OXIDE FUME OR DUST HAS BEEN ASSOCIATED WITH A BENIGN LUNG CONDITION CALLED SIDEROSIS, OR IRON PIGMENTATION WHICH DOES NOT RESULT IN ILLNESS.  ANIMAL STUDIES INDICATE THAT THE IRON OXIDE DUST DOES NOT CAUSE LUNG IMPAIRMENT OR FIBROSIS.  HOWEVER, WORKERS EXPOSED TO IRON OXIDE FUME IN THE PRESENCE OF SILICA MAY DEVELOP MIXED DUST PNEUMOCONIOSIS.  DIRECT CONTACT WITH DUST OR FUME MAY RESULT IN BURNS TO SKIN AND EYES AND MAY PRODUCE DAMAGE.

Potential Health Effects
 
Primary Routes of Exposure:
  Routes of entry for solids and liquids include eye and skin
  contact, ingestion and inhalation.  Routes of entry for gases
  include inhalation and eye contact.  Skin contact may be a route
  of entry for liquefied gases.
Acute Overexposure Effects:
  Contact with the eyes and skin may result in mechanical irritation.
  Inhalation may result in respiratory irritation.  Ingestion may
  result in gastric disturbances.
Chronic Overexposure Effects:
  Chronic overexposure to iron oxide fume or dust has been associated
  with x-ray changes of the lungs; however, it does not result in
  illness.  Changes are due to a benign lung condition called
  siderosis, or iron pigmentation.  Animal studies indicate that
  chronic overexposure to iron oxide dust does not cause lung
  impairment or fibrosis.  However, workers exposed to iron oxide fume
  in the presence of silica may develop mixed dust pneumoconiosis.
  Direct contact with dust or fume may result in burns to the skin and
  eyes and may produce damage.  There are no other known chronic 
  effects associated with this material.
First Aid Procedures - Aggravated Medical Conditions:
  Inhalation of dust could aggravate existing respiratory conditions.

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SECTION 4 - FIRST AID MEASURES
_______________________________________________________________________
First Aid Procedures - Skin:
  Wash affected areas immediately with soap and water.  Remove and launder
  contaminated clothing before reuse.  If irritation develops,
  get medical attention.
First Aid Procedures - Eyes:
  Immediately rinse eyes with running water for 15 minutes.  If
  irritation develops, get medical attention.
First Aid Procedures - Ingestion:
  If swallowed, dilute with water and immediately induce vomiting.
  Never give fluids or induce vomiting if the victim is unconscious or
  having convulsions. Get immediate medical attention.
First Aid Procedures - Inhalation:
  Move to fresh air.  Aid in breathing, if necessary, and get
  immediate medical attention.
First Aid Procedures - Notes to Physicians:
  None known.
First Aid Procedures - Aggravated Medical Conditions:
  Inhalation of dust could aggravate existing respiratory conditions.
First Aid Procedures - Special Precautions:
  None
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SECTION 5 - FIRE FIGHTING MEASURES
_______________________________________________________________________
                    Typical       Low/High     Deg.   Method

Flash Point:         NOT APPLICABLE
Autoignition:         NOT APPLICABLE
 
Fire and Explosion Data:  Possibility that hydrogen vapors and liquids can combust if temperature exceeds flashpoint. Avoid sparks and other sources of ignition.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
_______________________________________________________________________
General:
  Spills should be contained and placed in suitable containers for
  disposal in a licensed facility. This material is not regulated by
  RCRA or CERCLA ("Superfund"). Wear appropriate respiratory protection
  and protective clothing and provide adequate ventilation during
  clean-up.
Other Spill/Leak Procedures:
  No other spill procedures necessary.
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SECTION 7 - STORAGE AND HANDLING
_______________________________________________________________________
General:
 
Ensure adequate ventilation to minimize possible hydrogen accumulation.  When transferring this product
  make sure equipment is grounded to prevent electrostatic buildup and potential explosion.

Other Storage and Handling Data:
  No other specific storage requirements.

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SECTION 8 - PERSONAL PROTECTION
_______________________________________________________________________
Clothing:
  Gloves, coveralls, apron, boots as necessary to prevent skin contact.
Eyes:
  Chemical Goggles
Respiration:
  NIOSH/MSHA approved mist respirator as necessary.
Ventilation:
  Use local exhaust to control mists.
Explosion Proofing:
  See Section 4 - Fire and Explosion Data.
Other Personal Protection Data:
  None under normal conditions.
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SECTION 9 - PHYSICAL PROPERTIES
______________________________________________________________________
Color:  Black
Form/Appearance:  Paste or Suspension in Water
Odor:  Odorless
                          Typical             U.O.M.
Specific Gravity:     4.6
Bulk Density:    ~   5.2                 G/CC
pH:   7-9

Boiling Pt:  NOT AVAILABLE
Freezing Pt:  NOT AVAILABLE
Decomp. Tmp:  NOT AVAILABLE
Solubility in Water Description:  Insoluble


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SECTION 10 - STABILITY AND REACTIVITY
_______________________________________________________________________
Stability Data:
  This product is stable.
Incompatability:
  None known.
Conditions/Hazards to Avoid:
  None known.
Hazardous Decomposition/Polymerization:
  Polymerization: Does not occur.
Corrosive Properties:
  Not corrosive.
Oxidizer Properties:
  Not an oxidizer
Other Reactivity Data:
  None known.
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SECTION 11 - TOXICOLOGICAL INFORMATION
_______________________________________________________________________
Toxicity to Animals:
Rat, Oral LD50 - > 2000 MG/KG
(Data for a similar material)

Chronic Effects on Humans:
CARCINOGENIC EFFECTS:  Classified None. by NTP, None. by OSHA.  The substance is toxic to lungs, upper respiratory tract.
  (Data for a similar material.)
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SECTION 12 - ECOLOGICAL INFORMATION
_______________________________________________________________________
Products of Biodegradation:  
Possibly hazardous short term products are not likely.  However, long term degradation products may arise.

Toxicity of the Products of Biodegradation:   
The product itself and its products of degradation are not toxic.

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SECTION 13 - DISPOSAL CONSIDERATION
_______________________________________________________________________
Waste Disposal:
  The use and processing of this product, or addition of other constituents, may cause it to be considered a
  hazardous waste.  It is the waste generator's responsibility to determine if a particular waste is hazardous
  under RCRA.  Do not discharge into waterways or sewer systems.

Container Disposal:
  Dispose of in a licensed facility.  Recommend crushing or other means
  to prevent unauthorized reuse.

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SECTION 14 - TRANSPORTATION INFORMATION
_______________________________________________________________________
DOT Proper Shipping Name:
  N/A
DOT Technical Name:
  N/A
DOT Primary Hazard Class:
  N/A
DOT Secondary Hazard Class:
 
DOT Label Required:
  N/A
DOT Placard Required:
  N/A
DOT Poison Constituent:
 
Commodity Codes:                 UN/NA Code:        E/R Guide:
Bill of Lading Description:
  NOT REGULATED BY THE DEPARTMENT OF TRANSPORTATION
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SECTION 15 - REGULATORY INFORMATION
_______________________________________________________________________
Federal and State Regulations:

California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute:  Ferrosoferric Oxide

Massachusetts RTK: Ferrosoferric Oxide  

New Jersey :  Ferrosoferric Oxide  

New Jersey :  Ferrosoferric Oxide  

TSCA 8(b) Inventory: Ferrosoferric Oxide  

SARA Title III Section 3.3: Not Listed
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SECTION 16 - OTHER INFORMATION
_______________________________________________________________________
Hazard Ratings:
                     Health:    Fire:   Reactivity:  Special:
  HMIS                 1*        0         0            X

Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)
EINECS:  This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:
WHMIS ( Canada ): Class D-28 : Material causing other toxic effects.
DSCL (EEC): This product is not classified according to the EU regulations.
 

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION  CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE  ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE.  NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A  PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS.  IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE .  FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY POLYFLON HEREUNDER ARE GIVEN GRATIS AND POLYFLON ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK".

END OF DATA SHEET

 

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Manufactured b    y
Polyflon Company
A Crane Co. Company
One Willard Road
Norwalk, CT  06851 USA

©2004, Polyflon Company.  All rights reserved.